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  6. Lithium bis(trimethylsilyl)amide, 0.9-1.1M in hexane, packaged under Argon in resealable ChemSeal™ bottles, Thermo Scientific Chemicals

Lithium bis(trimethylsilyl)amide, 0.9-1.1M in hexane, packaged under Argon in resealable ChemSeal™ bottles, Thermo Scientific Chemicals

Product Code. 11314857
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Quantity:
100 g
500 g
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Description

CAS: 4039-32-1 | C6H18LiNSi2 | 167.327 g/mol

Lithium bis(trimetylsilyl)amide is used as a strong base in organic synthesis and as catalysts in polymerization reactions. It is also used to form various organolithium compounds such as acetylides and lithium enolates. It is a base employed in generating enolates for preparation of lactone precursors, pyranones and cyclohexanes. Further, it is used to catalyze the addition of phosphine P-H bonds to carbodiimides leading to phosphaguanidines. In addition, it is used in a three-step synthesis of disubstituted 1,2,5-thiadiazoles.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

  • Packaged under argon
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 4039-32-1
Molecular Formula C6H18LiNSi2
Molecular Weight (g/mol) 167.327
MDL Number MFCD00008261
InChI Key YNESATAKKCNGOF-UHFFFAOYSA-N
Synonym lithium bis trimethylsilyl amide, lithium hexamethyldisilazide, lihmds, lhmds, hexamethyldisilazane lithium salt, unii-rc4n1i108m, lithiumbis trimethylsilyl amide, lithium bis trimethylsilyl azanide, lithium hexamethyldisilazane, lithium bis-trimethylsilyl amide
PubChem CID 2733832
IUPAC Name lithium;bis(trimethylsilyl)azanide
SMILES [Li+].C[Si](C)(C)[N-][Si](C)(C)C

Specifications

Color Colorless to Yellow
Density 0.716 g/mL
Flash Point -31°C (-24°F)
Packaging ChemSeal™ bottles
Linear Formula [(CH3)3Si]2NLi
Quantity 500 g
UN Number UN2924
Beilstein 8136861
Sensitivity Air and moisture sensitive
Solubility Information Soluble in tetrahydrofuran,hexane and toluene.
Formula Weight 167.33
Physical Form Liquid
Chemical Name or Material Lithium bis(trimethylsilyl)amide
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