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1-(Trimethylsilyl)imidazole, 97%, Thermo Scientific Chemicals
CAS: 18156-74-6 | C6H12N2Si | 140.26 g/mol
268.00 SEK - 4020.00 SEK
Chemical Identifiers
CAS | 18156-74-6 |
---|---|
Molecular Formula | C6H12N2Si |
Molecular Weight (g/mol) | 140.26 |
MDL Number | MFCD00005280 |
InChI Key | YKFRUJSEPGHZFJ-UHFFFAOYSA-N |
Synonym | n-trimethylsilyl imidazole, 1-trimethylsilyl imidazole, 1-trimethylsilyl-1h-imidazole, tsim, 1h-imidazole, 1-trimethylsilyl, n-trimethylsilylimidazole, trimethylsilyl imidazole, 1-trimethylsilylimidazole, n-trimethylsilyl imidazol, imidazole, 1-trimethylsilyl |
PubChem CID | 28925 |
ChEBI | CHEBI:85063 |
IUPAC Name | imidazol-1-yl(trimethyl)silane |
SMILES | C[Si](C)(C)N1C=CN=C1 |
Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
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Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
11488710
|
Thermo Scientific Alfa Aesar
A12512.06 |
5 g |
268.00 SEK
5g |
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11444164
|
Thermo Scientific Alfa Aesar
A12512.18 |
50 g |
1210.00 SEK
50g |
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11498710
|
Thermo Scientific Alfa Aesar
A12512.22 |
100 g |
1940.00 SEK
100g |
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11454164
|
Thermo Scientific Alfa Aesar
A12512.30 |
250 g |
4020.00 SEK
250g |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
Description
1-(Trimethylsilyl)imidazole acts as a silylating agent for alcohols, carbohydrates and 1,3-dicarbonyl compounds. It is a derivatization reagent used for selective silylation of hydroxyl groups and carboxylic acid without affecting the amino group. It employed as an intermediate for the synthesis of imidazole derivatives. It plays an essential role to synthesize polysubstituted chiral spirotetrahydropyrans. It is also used in the quantification of pintol after derivatization by gas chromatography/ mass spectrometry.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications1-(Trimethylsilyl)imidazole acts as a silylating agent for alcohols, carbohydrates and 1,3-dicarbonyl compounds. It is a derivatization reagent used for selective silylation of hydroxyl groups and carboxylic acid without affecting the amino group. It employed as an intermediate for the synthesis of imidazole derivatives. It plays an essential role to synthesize polysubstituted chiral spirotetrahydropyrans. It is also used in the quantification of pintol after derivatization by gas chromatography/ mass spectrometry.
Solubility
Miscible with most common organic solvents. It decomposes in water.
Notes
Moisture and light sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong acids.
Chemical Identifiers
18156-74-6 | |
140.26 | |
YKFRUJSEPGHZFJ-UHFFFAOYSA-N | |
28925 | |
imidazol-1-yl(trimethyl)silane |
C6H12N2Si | |
MFCD00005280 | |
n-trimethylsilyl imidazole, 1-trimethylsilyl imidazole, 1-trimethylsilyl-1h-imidazole, tsim, 1h-imidazole, 1-trimethylsilyl, n-trimethylsilylimidazole, trimethylsilyl imidazole, 1-trimethylsilylimidazole, n-trimethylsilyl imidazol, imidazole, 1-trimethylsilyl | |
CHEBI:85063 | |
C[Si](C)(C)N1C=CN=C1 |
Specifications
18156-74-6 | |
0.956 | |
18°C (64°F) | |
C6H12N2Si | |
MFCD00005280 | |
606148 | |
n-trimethylsilyl imidazole, 1-trimethylsilyl imidazole, 1-trimethylsilyl-1h-imidazole, tsim, 1h-imidazole, 1-trimethylsilyl, n-trimethylsilylimidazole, trimethylsilyl imidazole, 1-trimethylsilylimidazole, n-trimethylsilyl imidazol, imidazole, 1-trimethylsilyl | |
YKFRUJSEPGHZFJ-UHFFFAOYSA-N | |
imidazol-1-yl(trimethyl)silane | |
28925 | |
140.26 | |
1-(Trimethylsilyl)imidazole |
-42°C | |
212°C | |
Weak | |
1.4765 | |
UN1993 | |
Moisture sensitive | |
Miscible with most common organic solvents. It decomposes in water. | |
C[Si](C)(C)N1C=CN=C1 | |
140.26 | |
CHEBI:85063 | |
97% |
Safety and Handling
GHS H Statement
H225-H315-H319-H335
Highly flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c
H225-H315-H319-H335
missing translation for 'dotInformation' : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
missing translation for 'einecsNumber' : 242-040-3
missing translation for 'rtecsNumber' : NI8700000
missing translation for 'tsca' : Yes
Recommended Storage : Ambient temperatures
- 1-(Trimethylsilyl)imidazole
Signal Word
- Danger
Hazard Category
- Acute toxicity Category 4
- LONG-TERM AQUATIC HAZARD Chronic 1
- Serious eye damage/eye irritation Category 1
- Flammable liquid Category 2
- Reproductive toxicity Category 1B
- Skin corrosion/irritation Category 1 C
Hazard Statement
- H225-Highly flammable liquid and vapour.
- H302-Harmful if swallowed.
- H314-Causes severe skin burns and eye damage.
- H318-Causes serious eye damage.
- H360D-May damage the unborn child.
- H410-Very toxic to aquatic life with long lasting effects.
Precautionary Statement
- P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
- P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P310-Immediately call a POISON CENTER/doctor/.
Supplemental information
- MIXTURE LIST-Contains : 1-(Trimethylsilyl)imidazole
RUO – Research Use Only
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